Please use this identifier to cite or link to this item: http://hdl.handle.net/10662/19834
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dc.contributor.authorFernández Marcos, Carlos María-
dc.contributor.authorGómez Neo, Ana María-
dc.contributor.authorDíaz Álvarez, Jesús-
dc.contributor.authorMartínez Caballero, Sonia-
dc.date.accessioned2024-02-02T21:41:11Z-
dc.date.available2024-02-02T21:41:11Z-
dc.date.issued2020-
dc.identifier.issn0021-9584-
dc.identifier.urihttp://hdl.handle.net/10662/19834-
dc.description.abstractRadical chemistry is an essential part of the organic chemistry curriculum. Free radical halogenation experiments provide an excellent opportunity to introduce important topics related to the outcome and mechanism of organic reactions. In this communication, a green photochemically activated benzylic bromination of p-toluic acid is described. In contrast with previous versions of this reaction, visible light provides the energy necessary to homolytically cleave the Br—Br bond and initiate the radical cascade. Thus, photochemical activation allows a safer, faster, and cheaper alternative to chemical free radical initiators. Furthermore, the reaction is conveniently performed in environmentally friendly acetonitrile, as a replacement for toxic and ozone-depleting chlorinated solvents, such as the usual carbon tetrachloride.es_ES
dc.format.mimetypeapplication/pdfen_US
dc.language.isoenges_ES
dc.publisherACS (American Chemical Society)-
dc.subjectQuímica Orgánica, Química Verde, Aprendizaje Prácticoes_ES
dc.subjectOrganic Chemistry, Green Chemistry, Hands-On Learninges_ES
dc.titleA safe and green benzylic radical bromination experimentes_ES
dc.typearticlees_ES
dc.description.versionpeerReviewedes_ES
europeana.typeTEXTen_US
dc.rights.accessRightsclosedAccesses_ES
europeana.dataProviderUniversidad de Extremadura. Españaes_ES
dc.identifier.bibliographicCitationMarcos, C. F.; Neo, A. G.; Díaz, J.; Martínez-Caballero, S., A Safe and Green Benzylic Radical Bromination Experiment. J. Chem. Educ. 2020, 97 (2), 582-585. doi: http://dx.doi.org/10.1021/acs.jchemed.9b00020es_ES
dc.type.versionpublishedVersiones_ES
dc.contributor.affiliationUniversidad de Extremadura. Departamento de Química Orgánica e Inorgánicaes_ES
dc.relation.publisherversionhttps://pubs.acs.org/doi/10.1021/acs.jchemed.9b00020es_ES
dc.identifier.doi10.1021/acs.jchemed.9b00020-
dc.identifier.publicationtitleJournal of Chemical Educationes_ES
dc.identifier.publicationissue2es_ES
dc.identifier.publicationfirstpage582es_ES
dc.identifier.publicationlastpage585es_ES
dc.identifier.publicationvolume97es_ES
dc.identifier.e-issn1938-1328-
dc.identifier.orcid0000-0003-2278-7118es_ES
dc.identifier.orcid0000-0003-2149-1489es_ES
dc.identifier.orcid0000-0001-9955-7818es_ES
dc.identifier.orcid0000-0002-4401-6165es_ES
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