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http://hdl.handle.net/10662/7502
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Campo DC | Valor | idioma |
---|---|---|
dc.contributor.author | Shi, Yan X. | |
dc.contributor.author | Liang, Rong Z. | |
dc.contributor.author | Martin, Katherine A. | |
dc.contributor.author | Star, Daniel G. | |
dc.contributor.author | Díaz Álvarez, Jesús | |
dc.contributor.author | Lin, Xin Y. | |
dc.contributor.author | Ganguly, Rakesh | |
dc.contributor.author | García García, Felipe | |
dc.date.accessioned | 2018-05-31T09:37:03Z | |
dc.date.available | 2018-05-31T09:37:03Z | |
dc.date.issued | 2015 | |
dc.identifier.issn | 1359-7345 | |
dc.identifier.uri | http://hdl.handle.net/10662/7502 | |
dc.description.abstract | Dimeric cyclophosphazanes [{P(μ-NR)}2(μ-NR)]2 [R = tBu ( 1) and iPr ( 3)] were oxidized with elemental selenium. During these reactions an unexpected C–N bond cleavage and N–H bond formation occurred. Compound 1 produced P4(μ-NtBu)3(μ-NH)3Se4 ( 2) where three tBu groups were lost in the form of isobutylene. In contrast, during the oxidation of the less sterically hindered 3, the resulting product, P4(μ-NiPr)5(μ-NH)Se4 ( 4), showed only one substituent loss. Theoretical studies confirmed the steric nature of the driving force underlying the different outcomes. | es_ES |
dc.description.sponsorship | Trabajo financiado por: Nanyang Technological University. Beca M4080552 | es_ES |
dc.format.extent | 4 p. | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | Royal Society of Chemistry | es_ES |
dc.rights | Atribución 3.0 España | * |
dc.rights.uri | http://creativecommons.org/licenses/by/3.0/es/ | * |
dc.subject | Dímeros ciclofosfazenos | es_ES |
dc.subject | Selenio | es_ES |
dc.subject | Isobutileno | es_ES |
dc.subject | Dimeric cyclophosphazanes | es_ES |
dc.subject | Selenium | es_ES |
dc.subject | Isobutylene | es_ES |
dc.title | Steric C-N bond activation on the dimeric macrocycle [{P(μ-NR)}2(μ-NR)]2 | es_ES |
dc.type | article | es_ES |
dc.description.version | peerReviewed | es_ES |
dc.rights.accessRights | openAccess | es_ES |
dc.subject.unesco | 2306 Química Orgánica | es_ES |
dc.subject.unesco | 2303 Química Inorgánica | es_ES |
dc.identifier.bibliographicCitation | Shi, Y. X.; Liang, R. Z.; Martin, K. A.; Star, D. G.; Díaz Álvarez, J.; Li, X. Y. y Ganguly, R. [et al.]. (2015). Steric C-N bond activation on the dimeric macrocycle [{P(μ-NR)}2(μ-NR)]2. Chemical communications, 51, 16468-16471. ESSN 1364-548X | es_ES |
dc.type.version | publishedVersion | es_ES |
dc.contributor.affiliation | Nanyang Technological University. Singapore | es_ES |
dc.contributor.affiliation | Universidad de Extremadura. Departamento de Química Orgánica e Inorgánica | es_ES |
dc.relation.publisherversion | https://doi.org/10.1039/C5CC06034F | es_ES |
dc.identifier.doi | 10.1039/C5CC06034F | |
dc.identifier.publicationtitle | Chemical communications | es_ES |
dc.identifier.publicationfirstpage | 16468 | es_ES |
dc.identifier.publicationlastpage | 16471 | es_ES |
dc.identifier.publicationvolume | 51 | es_ES |
Colección: | DQOIN - Artículos |
Archivos
Archivo | Descripción | Tamaño | Formato | |
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C5CC06034F.pdf | 1,72 MB | Adobe PDF | Descargar |
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